内窥镜检查在电站锅炉内部检验中的应用

工业内窥镜是电站锅炉内部检验中不可或缺的设备,主要用来对集箱、减温器、受热面管等内部人眼无法观察到的地方进行检验,从而确定承压部件内部是否存在严重影响锅炉安全运行的缺陷.本文通过对锅炉内窥实例进行分析和总结,阐述内窥镜检查在锅炉内检中的重要性并给相关工作人员提供借鉴与参考.     

南海湖非冰封期浮游植物群落生态特征及其与环境因子关系

分别于2017、2018年的非冰封期(5—10月)对南海湖的浮游植物群落和环境因子进行了调查。共发现浮游植物7门80属157种(含变种),其中绿藻门种数最多,其次是硅藻门和蓝藻门,时间上7月最多、10月最少,空间上呈东高西低、南高北低的趋势。浮游植物密度为23.35×10~6～126.00×10~6个/L,平均值为66.78×10~6个/L。主要优势种有微小平裂藻(Merismopedia tenuissima)、水华束丝藻(Aphanizomenon flosaquae)和螺旋弓形藻(Schroederia spiralis)。南海湖水质总体处于中污染状态。冗余分析表明,TN、TP、pH和温度是影响浮游植物分布的主要环境因子,绿藻门与TN关系密切,蓝藻门与TP、温度关系密切,硅藻门与pH关系密切。     

生态福利绩效视角下的上海市可持续发展评价研究

资源与环境约束加剧的大背景下,在"生态门槛"内实现社会福利最大化的可持续发展模式是未来城市发展的必然选择。从生态福利绩效视角出发,选取人均生态足迹和人类发展指数构建城市可持续发展评价指标体系,并采用DEA方法计算二者的投入产出效率,对上海市1999~2012年可持续发展水平进行多维度、动态化的实证分析。研究发现:1上海市人类发展指数、人均生态足迹与经济发展同步增长,但人均生态足迹水平大于生态承载能力,处于严重"生态赤字"状态,并不断恶化;2上海市多数年份的生态福利绩效处于DEA无效状态,且2005年以来进入规模收益递减通道。最后提出政策建议。     

石化行业的VOCs排放控制管理

概述了我国挥发性有机化合物（VOCs）的排放情况。介绍了国内外VOCs的管理现状。分析了国内石化行业VOCs排放控制管理中存在的主要问题以及污染物排放过程的类别。提出了明确定义、制定相关标准、完善分类管理体系、研究最佳的可行性控制技术等加强VOCs排放控制管理的对策和建议。     

Optimizing Cr(VI) adsorption on activated carbon produced from heavy oil fly ash

In order to explore the beneficial utilization of heavy oil fly ash (HOFA) generated in the power plants, the present study is intended to optimize the chromium(VI) [Cr(VI)] adsorption on activated carbon produced from HOFA. The raw HOFA obtained from a power plant was washed by nitric/hydrochloric acid and activated at 800 °C with a holding time of 60 min to produce fly ash activated carbon (FAC). Phosphoric acid was used as a chemical agent to improve the surface characteristics of the HOFA during the activation process. Batch adsorption experiments were employed to evaluate the effects of different parameters such as initial Cr(VI) concentration, pH, and FAC dose on the removal of Cr(VI) from aqueous solution. A total of 17 adsorption experimental runs were carried out employing the detailed conditions followed the response surface methodology based on the Box–Behnken design. The results indicate that developed FAC has the potential for removing Cr(VI) from wastewater. Under the test conditions, a maximum of 91.51 % Cr(VI) removal efficiency was achieved.     

洗涤剂去除上海青中有机磷农药的研究

研究了自制4种配方洗涤剂A、B、C、D在不同条件下对上海青(Brassica campestris L. ssp. Chinensis (L.) Makino)中残留的氧化乐果、敌百虫、乐果和甲胺磷的去除效果.借助GC-MS分析,结果表明: 在无外加条件下,洗涤剂A对4种有机磷农药的去除效果最佳,去除率达47.31%～64.24%;经超声波辅助处理,洗涤剂A的去除效果反而变差,且对乐果无去除效果,而洗涤剂B、C、D的去除效果均有提高,其中洗涤剂C对4种有机磷农药的平均去除率达86.03%,尤其对甲胺磷的去除率高达97.11%;经臭氧辅助处理,洗涤剂A的去除效果也降低,而洗涤剂B、C、D则相反,尤其是洗涤剂B,其对4种有机磷农药的平均去除率比无外加条件高43.13%.     

好氧颗粒污泥同时脱氮除磷技术研究

采用序批式活性污泥法(SBR)处理新疆油田公司准东石油基地污水,作为生物膜的一种特殊形式,介绍了该工艺的优点,在适宜的运行条件下进行实验。讨论了好氧颗粒污泥脱氮以及除磷的过程,分析了该工艺对氮、磷的去除率及好氧颗粒污泥在好氧、缺氧条件下的吸磷情况,当进水氨氮、磷和乙酸碳浓度分别为38.2 mg/L、27.7 mg/L和134.6 mg/L,MLSS和MLVSS分别为7.0 mg/L、6.4 mg/L时,氨氮、总无机氮、磷、乙酸碳的平均去除率分别达到98.8%、90.2%、98.9%、97.2%.     

An investigation on pollutant emissions from co-firing of RDF and coal

Pollutant emissions from co-firing of refuse derived fuel (RDF) and coal were investigated in a vortexing fluidized bed combustor (VFBC). RDF-5 was made of common municipal solid waste (MSW). CaCO₃ was injected in the combustor to absorb HCl at 850 °C. The results show that NO_x and HCl emissions increase with RDF-5 co-firing ratio. The NO_x concentration in flue gas at the bottom of the combustor is higher than that at the top. However, the trend of HCl released is reverse compared with NO_x emissions. It was found that the HCl concentration decreases with increasing the molar ratio of Ca/Cl. However, the effect of CaCO₃ addition on HCl retention is not significant when the molar ratio of Ca/Cl is higher than 5. The chlorine content in fly ash increases obviously with the molar ratio of Ca/Cl. PCDD/Fs emissions decrease slightly with an addition of CaCO₃. In this study incomplete combustion is regarded as the main cause for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) formation.     

Chemical compositions and sources of atmospheric PM10 in heating, non-heating and sand periods at a coal-based city in northeastern China

Mass concentrations and chemical components (18 elements, 9 ions, organic carbon [OC] and elemental carbon [EC]) in atmospheric PM(10) were measured at five sites in Fushun during heating, non-heating and sand periods in 2006-2007. PM(10) mass concentrations varied from 62.0 to 226.3 μg m(-3), with 21% of the total samples' mass concentrations exceeding the Chinese national secondary standard value of 150 μg m(-3), mainly concentrated in heating and sand periods. Crustal elements, trace elements, water-soluble ions, OC and EC represented 20-47%, 2-9%, 13-34%, 15-34% and 13-25% of the particulate matter mass concentrations, respectively. OC and crustal elements exhibited the highest mass percentages, at 27-34% and 30-47% during heating and sand period. Local agricultural residuals burning may contribute to EC and ion concentrations, as shown by ion temporal variation and OC and EC correlation analysis. Heavy metals (Cr, Ni, Zn, Cu and Mn) from coal combustion and industrial processes should be paid attention to in heating and sand periods. The anion/cation ratios exhibited their highest values for the background site with the influence of stationary sources on its upper wind direction during the sand period. Secondary organic carbon were 1.6-21.7, 1.5-23.0, 0.4-17.0, 0.2-33.0 and 0.2-21.1 μg m(-3), accounting for 20-77%, 44-88%, 4-77%, 8-69% and 4-73% of OC for the five sampling sites ZQ, DZ, XH, WH and SK, respectively. From the temporal and spatial variation analysis of major species, coal combustion, agricultural residual burning and industrial emission including dust re-suspended from raw material storage piles were important sources for atmospheric PM(10) in Fushun at heating, non-heating and sand periods, respectively. It was confirmed by principal component analysis that coal combustion, vehicle emission, industrial activities, soil dust, cement and construction dust and biomass burning were the main sources for PM(10) in this coal-based city.     

Assessment of heterogeneity of metal composition of fine particulate matter collected from eight U.S. counties using principal component analysis

The main objectives of this study are to (1) characterize chemical constituents of particulate matter (PM) and (2) compare overall differences in PM collected from eight US. counties. This project was undertaken as a part of a larger research program conducted by the Johns Hopkins Particulate Matter Research Center (JHPMRC). The goal of the JHPMRC is to explore the relationship between health effects and exposure to ambient PM of differing composition. The JHPMRC collected weekly filter-based ambient fine particle samples from eight US. counties between January 2008 and January 2010. Each sampling effort consisted of a 5-6-week sampling period. Filters were analyzed for 25 metals using inductively coupled plasma mass spectrometry (ICP-MS). Overall compositional differences were ranked by principal component analysis (PCA). The results showed that weekly concentrations of each element varied 3-40 times between the eight counties. PCA showed that the first five principal components explained 85% of the total variance. The authors found significant overall compositional differences in PM as the average of standardized principal component scores differed between the counties. These findings demonstrate PCA is a useful tool to identify the differences in PM compositional mixtures by county. These differences will be helpful for epidemiological and toxicological studies to help explain why health risks associated with PM exposure are different in locations with similar mass concentrations of PM.